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Pulsed laser deposition of ITO nanorods in argon and OLED applications

Identifieur interne : 000637 ( Main/Repository ); précédent : 000636; suivant : 000638

Pulsed laser deposition of ITO nanorods in argon and OLED applications

Auteurs : RBID : Pascal:13-0356407

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English descriptors

Abstract

Indium tin oxide (ITO) nanorods were deposited in argon gas environment on glass substrate at 250 °C by a pulsed Nd:YAG laser, with laser parameters of 10 Hz, 355 nm and 2-3 J/cm2. The formation of ITO nanorods was found to depend strongly on argon pressure and deposition duration, of (4-7) Pa and (30-60 min) respectively. At the initial growth stage, a large number of nucleation sites were first formed which eventually evolved into pin-needle types of nanorods. For extended period of deposition, oval-shaped lumps were seen to be formed among the nanorods. The growth of spherical tips in nanorods suggests the vapor-liquid-solid (VLS) mechanism. The XRD patterns show that ITO with In2O3 bixbyite structure is strongly orientated in <111> direction. The presence of ITO nanorods, however, was found to improve the organic light emitting diodes (OLED) performance with higher brightness and lower turn-on voltage, as compared to OLED fabricated with commercial ITO. ITO samples were also deposited in N2 but nanorod was not observed and its OLED failed to operate.

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Pascal:13-0356407

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<title xml:lang="en" level="a">Pulsed laser deposition of ITO nanorods in argon and OLED applications</title>
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<name sortKey="Tan, Sek Sean" uniqKey="Tan S">Sek-Sean Tan</name>
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<div type="abstract" xml:lang="en">Indium tin oxide (ITO) nanorods were deposited in argon gas environment on glass substrate at 250 °C by a pulsed Nd:YAG laser, with laser parameters of 10 Hz, 355 nm and 2-3 J/cm
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. The formation of ITO nanorods was found to depend strongly on argon pressure and deposition duration, of (4-7) Pa and (30-60 min) respectively. At the initial growth stage, a large number of nucleation sites were first formed which eventually evolved into pin-needle types of nanorods. For extended period of deposition, oval-shaped lumps were seen to be formed among the nanorods. The growth of spherical tips in nanorods suggests the vapor-liquid-solid (VLS) mechanism. The XRD patterns show that ITO with In
<sub>2</sub>
O
<sub>3</sub>
bixbyite structure is strongly orientated in <111> direction. The presence of ITO nanorods, however, was found to improve the organic light emitting diodes (OLED) performance with higher brightness and lower turn-on voltage, as compared to OLED fabricated with commercial ITO. ITO samples were also deposited in N
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